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We don’t allow that by default since that would lead to mass diffusion into the surface. If that’s what you want, we’d need a way to enforce that the sum of the species diffusion fluxes was zero. You could do that, but the proper way would likely be problem-dependent at best.
OTOH, if you cylinder surface wasn’t actually meant to be a material boundary, but rather a numerical interface into another domain or some such idea, you may want this. So maybe it’s best to ask what your plans were.
if we have a cylinder in the domain, can i fix the mass fraction of species on the cylinder like fix the temperature?
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